Tuesday, June 1, 2010

Collison Theory PPT

Collision theory is a theory proposed by Max Trautz[1] and William Lewis in 1916 and 1918, that qualitatively explains how chemical reactions occur and why reaction rates differ for different reactions.[2] This theory is based on the idea that reactant particles must collide, but only a certain fraction of the total collisions have the energy to connect effectively and cause the reactants to transform into the products. This is because only a portion of the molecules have enough energy and the right orientation (or "angle") at the moment of impact to break any existing bonds and form new ones. The minimal amount of energy needed for this to occur is known as activation energy. If the elements react with each other, the collision is called successful, but if the concentration of at least one of the elements is too low, there will be fewer particles for the other elements to react with and the reaction will happen much more slowly. As temperature increases, the average kinetic energy and speed of the molecules increases but this only slightly increases the number of collisions. The rate of the reaction increases with temperature increase because a higher fraction of the collisions overcome the activation energy.

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